General InformationPublicationsResearch Projects

  • C. S. Spanjers, P. Guillo, M. J. Janik, T. D. Tilley and Robert M Rioux, 2017, "Identification of second shell coordination in transition metal species using theoretical XANES: Examples of Ti-O-(C, Si, Ge) molecular complexes", J. Phys. Chem. C, 121, pp. 162-167
  • C S Spanjers, A Dasgupta, M Kirkham, B Burger, G Kumar, Michael J Janik and Robert M Rioux, 2017, "Determination of Bulk and Surface Atomic Arrangement in Ni-Zn Gamma Brass Phase at Different Ni to Zn Ratios", Chem. Mater., 29, pp. 504-512
  • A Sathe, A Nambiar and Robert M Rioux, 2017, "Synthesis of cyclic organic carbonates via catalytic oxidative carboxylation of olefins in flow reactors", Catal. Sci. Technol., 7, pp. 84-89
  • Robert M Rioux, 2016, "Analysis of Isothermal Titration Calorimetry Data"
  • Robert M Rioux, 2016, "Catalysis for the Production of Renewable Energy"
  • C S Sievers, Y Noda, L Qi, E M Albuquerque, Robert M Rioux and S L Scott, 2016, "Phenomena in Catalytic Reactions at Solid-Liquid Interfaces", ACS Catalysis, 6, pp. 8286-8307
  • S G Turney, M Ahmed, I Chandrsekar, R B Wysolmerski, Z M Goeckeler, Robert M Rioux, G M Whitesides and P C Bridgman, 2016, "Nerve growth factor stimulates axon outgrowth through negative regulation of growth cone actomyosin restraint of microtubule advance", Molecular Biology of the Cell, (27), pp. 500-517
  • A Gellman, Robert M Rioux and P Stair, 2016, "Editorial: Special issue dedicated to Gabor Somorjai’s 80th birthday", Surf. Sci., (648), pp. 1
  • J Saavedra, T Whittaker, Z Chen, C J Pursell, Robert M Rioux and B D Chandler, 2016, "Controlling activity and selectivity using water in the Au-catalyzed preferential oxidation in CO in H2", Nature Chem, (8), pp. 585-590
  • Y Noda, K Li, A Engler, W A Elliot and Robert M Rioux, 2016, "Development of Robust Sulfur Quantification and Speciation Method for SBA-15 Supported Sulfonic Acid Catalysts", Catal. Sci. Technol., (6), pp. 5961-5971
  • Davood Babaei Pourkargar, Seyed Mehdi Kamali Shahri, Robert M Rioux and Antonios Armaou, 2016, "Spatiotemporal Modeling and Parametric Estimation of Isothermal CO2 Adsorption Columns", Ind. Eng. Chem. Res., (55), pp. 6443-6453
  • B. Panthi, A. Mukopadhyay, L. Tibbitts, J. Saavedra, C. J. Pursell, Robert M Rioux and B. D. Chandler, 2015, "Using Thiol Adsorption on Supported Au Nanoparticle Catalysts to Evaluate Au Dispersion and the Number of Active Sites for Benzyl Alcohol Oxidation", ACS Catal, 5, pp. 2232-2241
  • Robert M Rioux and F. D. Toste, 2015, "Catalysis Science and Technology: Catalysis in the USA", Catal Sci Technol, 5, pp. 1357-1359
  • Charles S Spanjers, Richard S Sim, Nicholas P Sturgis and Robert M Rioux, 2015, "In-situ Characterization of Ni1-xZnx/ZnO Catalysts and their Selectivity for Acetylene Semihydrogenation in Excess Ethylene", ACS Catal., 5, pp. 11
  • Robert M Rioux, 2015, "Catalysis within Nanoconfined Spaces"
  • Robert M Rioux, 2014, "XAFS Techniques for Catalysts, Nanomaterials, and Surfaces"
  • A. Sathe, M. A. Peck, C. Balasanthiran, M. A. Langell, Robert M Rioux and J. D. Hoefelmeyer, 2014, "X-ray photoelectron spectroscopy of transition metal ions attached to the surface of rod-shape anatase TiO2 nanocrystals", Inorganica Chimica Acta, 422, pp. 8-13
  • D. Childers, N. M. Schweitzer, S. M. Kamali Shahri, Robert M Rioux, J. T. Miller and R. J. Meyer, 2014, "Evidence for Geometric Effects in Neopentane Conversion on PdAu Catalysts", Catal Sci Technol, 4, pp. 4366-4377
  • D. Childers, S. M. Kamali Shahri, N. Schweitzer, Robert M Rioux, J. T. Miller and R. J. Meyer, 2014, "Modifying structure-sensitive reactions by addition of Zn to Pd", J. Catal, 318, pp. 75-84
  • C. S. Spanjers, T. P. Senftle, A. C. T. van Duin, Michael J Janik, A. I. Frenkel and Robert M Rioux, 2014, "Illuminating Surface Atoms in Nanoclusters by Differential X-ray Absorption Spectroscopy", Phys. Chem. Chem. Phys., 16, pp. 26528-26538
  • Y. Yang and Robert M Rioux, 2014, "Highly Stereoselective Anti-Markovnikov Hydrothiolation of Alkynes and Electron-Deficient Alkenes by a Supported Cu-NHC Complex.", Green Chem, 16, pp. 3916-3925
  • S. M. McCarthy, Y. C. Lin, D. Devarajan, J. W. Chang, H. Yennawar, Robert M Rioux, D. H. Ess and A. T. Radosevich, 2014, "Intermolecular N-H Oxidative Addition of Ammonia, Alkylamines and Arylamines to a Planar ?3-Phosphorus Compound via an Entropy-Controlled Electrophlic Mechanism.", J. Am. Chem. Soc., 136, pp. 4640-4650
  • E. G. Moschetta, K. M. Gans and Robert M Rioux, 2014, "Elucidating the Roles of Enthalpy, Entropy, and Donor Atom in the Chelate Effect for Binding Different Bidentate Ligands on the Same Metal Center", Journal of Catalysis 309, pp. 11-20
  • M. A. Smith, A. Zoelle, Y. Yang, Robert M Rioux, N. Hamilton, K. Amakawa, P. K. Nielsen and A. Trunschke, 2014, "Surface roughness effects in the catalytic behavior of vanadia supported on SBA-15.", J. Catal., 312, pp. 170-178
  • M. Strayer, J. M. Binz, M. Tanase, S. M. Kamali Shahri, R. Sharma, Robert M Rioux and T. E. Mallouk, 2014, "Interfacial bonding stabilizes rhodium and rhodium oxide nanoparticles on layered Nb- and Ta oxide supports.", J. Am. Chem. Soc., 136, pp. 5687-5696
  • C. S. Spanjers, J. T. Held, M. J. Jones, D. D. Stanley, R. S. Sim, Michael J Janik and Robert M Rioux, 2014, "Zinc Inclusion to Heterogeneous Nickel Catalysts Reduces Oligomerization during the Semihydrogenation of Acetylene.", J. Catal., 316, pp. 164-173
  • M. H. Do, T. Wang, Dang-Guo Cheng, Robert M Rioux and J. Gong, 2014, "Simple Strategies for Fabrication of a Periodic Mesoporous Aluminosilicate with Crystalline Walls", Small, 10, pp. 4249-4256
  • V. Ravi, J. M. Binz and Robert M Rioux, 2013, "Thermodynamic Profiles at the Solvated Inorganic-Organic Interface: The case of Gold-Thiolate Monolayers", Nano Lett., 13, pp. 4442-4448
  • E. G. Moschetta, Kristina M. Gans and Robert M Rioux, 2013, "Characterization of sites of different thermodynamic affinities on the same metal center via isothermal titration calorimetry", Journal of Catalysis, 302, pp. 1-9
  • Y. Yang, Eric G. Moschetta and Robert M Rioux, 2013, "Addition of Sulfonic Acids to Terminal Alkynes Catalyzed by a Rhodium Complex: Ligand Concentration-Controlled Reaction Selectivity", ChemCatChem, 5, pp. 3005-3013
  • W. Kang, C. S. Spanjers, Robert M Rioux and J. D. Hoefelmeyer, 2013, "Synthesis of brookite TiO2 nanorods with isolated Co(II) surface sites and photocatalytic degradation of 5,8-dihydroxy-1,4-naphthoquinone dye", J. Mater. Chem. A, 1, pp. 7717-7728
  • S. Jana, J. W. Chang and Robert M Rioux, 2013, "Synthesis and Modeling of Hollow Intermetallic Ni-Zn Nanoparticles Formed by the Kirkendall Effect", Nano Lett., 13, pp. 3618-3625
  • D. Childers, A. Saha, N. Schweitzer, Robert M Rioux, J. T. Miller and R. J. Meyer, 2013, "Correlating Heat of Adsorption to Reaction Selectivity: Size Effects in Neopentane Isomerization over Pt and Pd Catalyst", ACS Catal., 3, pp. 2487-2496
  • P. Cordeiro, P. Guillo, C. S. Spanjers, J. W. Chang, M. Lipschutz, M. Fasulo, Robert M Rioux and T. D. Tilley, 2013, "Titanium-Germoxy Precursor Route to Germanium-Modified Epoxidation Catalysts with Enhanced Activity", ACS Catal., 3, pp. 2269-2279
  • Y. Yang, W. Dong, Y. Guo and Robert M Rioux, 2013, "Cu(I)-Catalyzed Aerobic Cross-Dehydrogenative Coupling of Terminal Alkynes with Thiols for Construction of Alkynyl Sulfides", Green Chem., 15, pp. 3170-3175
  • S. Janna and Robert M Rioux, 2012, "Seeded Growth Induced Amorphous to Crystalline Transformation of Niobium Oxide Nanostructures", Nanoscale, 4, pp. 1782-1788
  • S. J. Kweskin, Robert M Rioux, H. Song, K. Komvopoulos, P. Yang and G. A. Somorjai, 2012, "High-Pressure Adsorption of Ethylene on Cubic Pt Nanoparticles and Pt(100) Single Crystals Probed by in Situ Sum Frequency Generation Vibrational Spectroscopy", ACS Catal., 2, pp. 2377-2386
  • Robert M Rioux, 2012, "Atomically Precise Methods for Synthesis of Solid Catalysts"
  • Yeon S. Choi, Eric G. Moschetta, Jeffrey T. Miller, Meg Fasulo, Meredith J. McMurdo, Robert M Rioux and T. Don Tilley, 2011, "Highly Dispersed Pd-SBA15 Materials from Tris(tert-butoxy)siloxy Complexes of Pd(II)", ACS Catalysis 1, pp. 1166-1177
  • Y. Yang and Robert M Rioux, 2011, "Highly regio- and stereoselective hydrothiolation of acetylenes with thiols catalyzed by a well-defined supported Rh complex", Chemical Communications, 47, pp. 6557-6559
  • J. Gong and Robert M Rioux, 2011, "Heterogeneous catalysis by metals: New synthetic methods and characterization techniques for high reactivity preface", Catalysis Today, 160, pp. 1-2
  • S. Eldahj, Robert M Rioux, M. D. Dickey, J. J. DeYoreo and G. M. Whitesides, 2010, "Subnanometer Replica Molding of Molecular Steps on Ionic Crystals", Nano Lett., pp. 4140-4145
  • Robert M Rioux, 2010, Model Systems in Catalysis: Single Crystals to Supported Enzyme Mimics, Springer, pp. 526
  • N. Chen, Robert M Rioux, Luis A. M. M. Barbosa and F. H. Ribeiro, 2010, "Kinetic and Theoretical Study of the Hydrodechlorination of CH4-xClx (x=1-4) Compounds on Palladium", Langmuir, 26, pp. 16615-16624
  • S. H. Kim, F. H. Ribeiro and Robert M Rioux, 2010, "Preface to the Molecular Surface Chemistry and Its Applications Special Issue", Langmuir, 26, pp. 16187-16189
  • D. J. Lipomi, R. V. Martinez, Robert M Rioux, L. Cademartiri, W. F. Reus and G. M. Whitesides, 2010, "Survey of Materials for Nanoskiving and Influence of the Cutting Process on the Nanostructures Produced", ACS Applied Materials and Interfaces, 2, pp. 2503-2514
  • M. E. Grass, Robert M Rioux and G. A. Somorjai, 2009, "Dependence of gas-phase crotonaldehyde hydrogenation selectivity and activity on the size of Pt nanoparticles (1.7-7.1 nm) supported on SBA-15", Catal. Lett., 128, pp. 1-8
  • J. Gingras, Robert M Rioux, D. Cuvelier, N. A. Geisse, L. Mahadevan, J. W. Lichtman, G. M. Whitesides and J. R. Sanes, 2009, "Controlling the Orientation and Synaptic differentiation of Myotubes with Micropatterned Substrates", Biophysical Journal, 97, pp. 2771-2779
  • Robert M Rioux, 2009, "Liquid Phase Oxidation via Heterogeneous Catalysis"
  • Robert M Rioux, J. D. Hoefelmeyer, M. Grass, H. Song, K. Niesz, P. D. Yang and G. A. Somoraji, 2008, "Adsorption and co-adsorption of ethylene and carbon monoxide on silica-supported monodisperse Pt nanoparticles. Volumetric adsorption and infrared spectroscopy studies", Langmuir, 24, pp. 198-207
  • Robert M Rioux, H. Song, M. Grass, J. D. Hoefelmeyer, K. Niesz, P. D. Yang and G. A. Somoraji, 2008, "Kinetics and mechanism of the poisoning of ethylene hydrogenation by CO on silica-supported monodisperse Pt nanoparticles", J. Catal., 254, pp. 1-11
  • M. E. Grass, Y. Yue, S. E. Habas, Robert M Rioux, C. I. Teall, P. Yang and G. A. Somorjai, 2008, "Silver ion mediated shape control of platinum nanoparticles: Removal of silver by selective etching leads to increased catalytic activity", J. Phys. Chem. C, 112, pp. 4797-4804
  • D. A. Ruddy, J. Jarupatrakorn, Robert M Rioux, J. T. Miller, M. J. McMurdo, K. A. Tupper and T. D. Tilley, 2008, "Site-Isolated Pt-SBA15 Materials from Tris(tert-butoxy)siloxy Complexes of Pt(II) and Pt(IV)", Chem. Mater., 20, pp. 6517-6527
  • Robert M Rioux, B. Hsu, M. E. Grass, H. Song and G. A. Somorjai, 2008, "Influence of particle size on reaction selectivity in cyclohexene hydrogenation and dehydrogenation over silica-supported monodisperse Pt particles", Catal. Lett., 126, pp. 10-19
  • Q. Xu, Robert M Rioux, M. D. Dickey and G. M. Whitesides, 2008, "Nanoskiving: A New Method to Produce Nanomaterials", Acc. Chem. Res., 41, pp. 1566-1577
  • T. J. Toops, W. N. Delgass and Robert M Rioux, 2007, "M. Albert Vannice Festschrift", Catal. Today, 123, pp. 2-5
  • Q. Xu, J. Bao, Robert M Rioux, R. Perez-Castejillos, F. Capasso and G. M. Whitesides, 2007, "Fabrication of Large-Area Patterned Nanostructures for Optical Applications by Nanoskiving", Nano Lett., 7, pp. 2800-2805
  • Q. Xu, Robert M Rioux and G. M. Whitesides, 2007, "Fabrication of Complex Nanostructures by Nanoskiving", ACS Nano, 1, pp. 215-221
  • Robert M Rioux, H. Song, P. Yang and G. A. Somoraj, 2007, Platinum Nanoclusters: Size and Shape Surface Structure Sensitivity of Catalytic Reactions, Elsevier
  • M. Yang, Robert M Rioux and G. A. Somorjai, 2006, "Reaction kinetics and in-situ sum frequency generation surface vibrational spectroscopy studies of cycloalkene hydrogenation/ dehydrogenation on Pt(111): substituent effects and CO poisoning mechanism", J. Catal., 237, pp. 255-266
  • H. Song, Robert M Rioux, J. D. Hoefelmeyer, R. Komor, K. Niesz, M. Grass, P. Yang and G. A. Somorjai, 2006, "Hydrothermal growth of mesoporous SBA-15 silica in the presence of PVP-stabilized Pt nanoparticles: Synthesis, characterization, and catalytic properties", J. Am. Chem. Soc., 128, pp. 3027-3037
  • G. A. Somorjai, A. M. Contreras, M. Montano and Robert M Rioux, 2006, "Clusters, Surfaces, and Catalysis", Proc. Nat. Acad., U. S. A, 103, pp. 10577-83
  • S. Kweskin, Robert M Rioux, S. E. Habas, K. Komvopoulos, P. Yang and G. A. Somorjai, 2006, "Carbon Monoxide Adsorption and Oxidation on Monolayer Films of Cubic Platinum Nanoparticles Investigated by Infrared-Visible Sum Frequency Generation Vibrational Spectroscopy", J. Phys. Chem. B, 110, pp. 15920-15925
  • Robert M Rioux, H. Song, M. Grass, S. Habas, K. Niesz, J. D. Hoefelmeyer, P. Yang and G. A. Somorjai, 2006, "Monodisperse platinum nanoparticles of well-defined shape: Synthesis, characterization, catalytic properties and future prospects", Top. Catal., 39, pp. 167-174
  • Robert M Rioux, A. L. Marsh, J. S. Gaughan and G. A. Somorjai, 2006, "Oxidation and reforming reactions of methane on a stepped Pt(557) single crystal", Catal. Today, 123, pp. 265-275
  • Robert M Rioux, H. Song, J. D. Hoefelmeyer, P. Yang and G. A. Somorjai, 2005, "High-Surface-Area Catalyst Design: Synthesis, Characterization, and Reaction Studies of Platinum Nanoparticles in Mesoporous SBA-15 Silica", J. Phys. Chem. B, 109, pp. 2192-2202
  • G. A. Somorjai and Robert M Rioux, 2005, "High Technology Catalysts Towards 100% Selectivity. Fabrication, Characterization, and Reaction Studies", Catalysis Today, 100, pp. 201-215
  • Robert M Rioux and M. A. Vannice, 2005, "Dehydrogenation of isopropyl alcohol on carbon-supported Pt and Cu-Pt catalysts", J. Catal., 233, pp. 147-165
  • Y. Yin, Robert M Rioux, C. K. Erdonmez, S. Hughes, G. A. Somorjai and A. P. Alivisatos, 2004, "Formation of Hollow Nanocrystals through the Nanoscale Kirkendall Effect", Science, 304, pp. 711-714
  • N. Chen, Robert M Rioux and F. H. Ribeiro, 2004, "Hydrodechlorination reactions of 2-chloro-1,1,1,2-tetrafluoroethane and chloroethane in H2 and D2 on Pd catalysts", Appl. Catal. A-Gen, 271, pp. 85-94
  • G. A. Somorjai, Robert M Rioux and J. Grunes, 2003, Fabrication of Two-Dimensional and Three-Dimensional Platinum Nanoclusters to Serve as High Technology Catalysts - Catalysts Capable of 100% Reaction Selectivity, World Scientific, pp. 97-125
  • Robert M Rioux and M. A. Vannice, 2003, "Hydrogenation/dehydrogenation: Isopropanol dehydrogenation over copper catalysts", J. Catal., 216, pp. 362-376
  • N. Chen, Robert M Rioux and F. H. Ribeiro, 2002, "Investigation of Reaction Steps for the Hydrodechlorination of Chlorine-Containing Organic Compounds on Pd Catalysts", J. Catal., 211, pp. 192-197
  • K. O. Nowack, Robert M Rioux, C. Na, X. Wu and L. R. Radovic, 2001, "A commentary on "Effect of metal additives on the physico-chemical characteristics of activated carbon exemplified by benzene and acetic acid adsorption", Carbon, 39, pp. 951-953
  • C. D. Thompson, Robert M Rioux, N. Chen and F. H. Ribeiro, 2000, "Turnover Rate, Reaction Order and Elementary Steps for the Hydrodechlorination of Chlorofluorocarbons on Palladium Catalysts", J. Phys. Chem. B, 104, pp. 3067-3077
  • Robert M Rioux, C. D. Thompson, N. Chen and F. H. Ribeiro, 2000, "Hydrodechlorination of chlorofluorocarbons CF3-CFCl2 and CF3-CCl3 over Pd/C and Pd black catalysts", Catal. Today, 62, pp. 269-278
  • M. E. Strayer, T. P. Senftle, J. P. Winterstein, N. M. Vargos-Barbosa, R. Sharma, Robert M Rioux, Michael J Janik and T. E. Mallouk, , "Charge Transfer Stabilization of Late Transition Metal Oxide Nanoparticles on a Layered Support", J. Am. Chem. Soc., 137, pp. 8


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