Department Personnel
Dow Professor James Vrentas | Published book, Diffusion and Mass Transfer
Title: Diffusion and Mass Transfer
Authors: James S. Vrentas and
Christine M. Vrentas
Publication:
December 12, 2012
CRC Press
644 pages
Table of Contents
Introduction
- Generalized Transport Phenomena Approach to Problem Analysis
- General Content
Conservation Laws and Field Equations
- Concentrations, Velocities, and Fluxes
- Thermodynamics of Purely Viscous Fluid Mixtures
- Conservation of Mass for a One-Component System
- Conservation of Mass for a Mixture
- Modification of Field Equations for Mass Transfer
- Conservation of Linear Momentum for One-Component Systems
- Conservation of Linear Momentum for a Mixture
- Conservation of Moment of Momentum for One-Component Systems
- Conservation of Moment of Momentum for a Mixture
- Strategies for the Solution of Mass Transfer Problems
Boundary Conditions
- Definitions
- Jump Balances for Mass Conservation
- Jump Balances for Linear Momentum Conservation
- Postulated Boundary Conditions at Phase Interfaces
- Boundary Conditions in the Absence of Mass Transfer
- Utilization of Jump Balances
- Additional Comments on Boundary Conditions
- Boundary Conditions and Uniqueness of Solutions
Constitutive Equations
- Constitutive Principles
- First-Order Theory for Binary Systems
- Combined Field and Constitutive Equations for First-Order Binary Theory
- First-Order Theory for Ternary Systems
- Special Second-Order Theory for Binary Systems
- Viscoelastic Effects in Flow and Diffusion
- Validity of Constitutive Equations
Parameters in Constitutive Equations
- General Approach in Parameter Determination
- Diffusion in Polymer–Solvent Mixtures
- Diffusion in Infinitely Dilute Polymer Solutions
- Diffusion in Dilute Polymer Solutions
- Diffusion in Concentrated Polymer Solutions - Free-Volume Theory for Self-Diffusion
- Diffusion in Concentrated Polymer Solutions - Mutual Diffusion Process
- Diffusion in Crosslinked Polymers
- Additional Properties of Diffusion Coefficients
Special Behaviors of Polymer–Penetrant Systems
- Volumetric Behavior of Polymer–Penetrant Systems
- Sorption Behavior of Polymer–Penetrant Systems
- Antiplasticization
- Nonequilibrium at Polymer–Penetrant Interfaces
Mathematical Apparatus
- Basic Definitions
- Classification of Second-Order Partial Differential Equations
- Specification of Boundary Conditions
- Sturm–Liouville Theory
- Series and Integral Representations of Functions
- Solution Methods for Partial Differential Equations
- Separation of Variables Method
- Separation of Variables Solutions
- Integral Transforms
- Similarity Transformations
- Green's Functions for Ordinary Differential Equations
- Green's Functions for Elliptic Equations
- Green's Functions for Parabolic Equations
- Perturbation Solutions
- Weighted Residual Method
Solution Strategy for Mass Transfer Problems
- Proposed Solution Methods
- Induced Convection
Solutions of a General Set of Mass Transfer Problems
- Mixing of Two Ideal Gases
- Steady Evaporation of a Liquid in a Tube
- Unsteady-State Evaporation
- Analysis of Free Diffusion Experiments
- Dissolution of a Rubbery Polymer
- Bubble Growth from Zero Initial Size
- Stability Behavior and Negative Concentrations in Ternary Systems
- Analysis of Impurity Migration in Plastic Containers
- Efficiency of Green's Function Solution Method
- Mass Transfer in Tube Flow
- Time-Dependent Interfacial Resistance
- Laminar Liquid Jet Diffusion Analysis
- Analysis of the Diaphragm Cell
- Dissolved Organic Carbon Removal from Marine Aquariums
- Unsteady Diffusion in a Block Copolymer
- Drying of Solvent-Coated Polymer Films
- Flow and Diffusion Past a Flat Plate with Solid Dissolution
- Gas Absorption in Vertical Laminar Liquid Jets
- Utilization of Polymers in Drug Delivery
- Gas Absorption and Diffusion into a Falling Liquid Film
Perturbation Solutions of Mass Transfer Moving Boundary Problems
- Dissolution of a Plane Surface of a Pure Gas Phase
- Bubble Dissolution
- Singular Perturbations in Moving Boundary Problems
- Dropping Mercury Electrode
- Sorption in Thin Films
- Numerical Analysis of Mass Transfer Moving Boundary Problems
Diffusion and Reaction
- Design of a Tubular Polymerization Reactor
- Transport Effects in Low-Pressure CVD Reactors
- Solution of Reaction Problems with First-Order Reactions
- Plug Flow Reactors with Variable Mass Density
- Bubble Dissolution and Chemical Reaction
- Danckwerts Boundary Conditions for Chemical Reactors
Transport in Nonporous Membranes
- Assumptions Used in the Theory for Membrane Transport
- Steady Mass Transport in Binary Membranes
- Steady Mass Transport in Ternary Membranes
- Unsteady Mass Transport in Binary Membranes
- Phase Inversion Process for Forming Asymmetric Membranes
- Pressure Effects in Membranes
Analysis of Sorption and Desorption
- Derivation of a Short-Time Solution Form for Sorption in Thin Films
- Sorption to a Film from a Pure Fluid of Finite Volume
- A General Analysis of Sorption in Thin Films
- Analysis of Step-Change Sorption Experiments
- Integral Sorption in Glassy Polymers
- Integral Sorption in Rubbery Polymers
- Oscillatory Diffusion and Diffusion Waves
Dispersion and Chromatography
- Formulation of Taylor Dispersion Problem
- Dispersion in Laminar Tube Flow for Low Peclet Numbers
- Dispersion in Laminar Tube Flow for Long Times
- Dispersion in Laminar Tube Flow for Short Times
- Analysis of an Inverse Gas Chromatography Experiment
Effects of Pressure Gradients on Diffusion: Wave Behavior and Sedimentation
- Wave Propagation in Binary Fluid Mixtures
- Hyperbolic Waves
- Dispersive Waves
- Time Effects for Parabolic and Hyperbolic Equations
- Sedimentation Equilibrium
Viscoelastic Diffusion
- Experimental Results for Sorption Experiments
- Viscoelastic Effects in Step-Change Sorption Experiments
- Slow Bubble Dissolution in a Viscoelastic Fluid
Transport with Moving Reference Frames
- Relationships Between Fixed and Moving Reference Frames
- Field Equations in Moving Reference Frames
- Steady Diffusion in an Ultracentrifuge
- Material Time Derivative Operators
- Frame Indifference of Material Time Derivatives
- Frame Indifference of Velocity Gradient Tensor
- Rheological Implications
Appendix: Vector and Tensor Notation
- General Notation Conventions
- Vectors
- Tensors
- Results for Curvilinear Coordinates
- Material and Spatial Representations
- Reynolds' Transport Theorem